Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Predicting quantiles of water quality from catchment characteristics     

Danlu Guo  Shuci Liu  Dhananjay Singh  Andrew W. Western 《水文研究》2021,35(1):e13996

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

Geography Deserts: State and Regional Variation in the Formal Opportunity to Learn Geography in the United States, 2005–2015     

Mark C. Jones  Marcos Luna 《The Journal of geography》2019,118(2):88-100

The formal opportunity to learn geography in the United States is unevenly distributed across space, creating possible geography deserts. Data on the number of exams taken in Advanced Placement Human Geography (APHG) and bachelor’s degrees earned in geography are mapped at the state and regional scales. Normalized rates are ranked and grouped into quintiles. For APHG exams, states in the southeastern region of the United States are in the uppermost quintiles while states in the northeastern region are in the lowermost quintiles. The pattern for bachelor’s degrees in geography is somewhat the spatial inverse of that for APHG.  相似文献   

基于F-范数的不确定性平差模型的解算方法     

鲁铁定  朱国红 《大地测量与地球动力学》2018,38(6):557-561

为提高基于F-范数的不确定性平差模型的解算效率，给出直接迭代算法进行参数估计。该算法无需SVD，解算过程简单且易于编程计算，同时给出迭代不收敛时的SVD-解方程算法。二元线性拟合及沉降观测AR模型的算例结果表明，这2种算法正确可行，与SVD-迭代算法具有等价性。当迭代收敛时，宜使用直接迭代算法，收敛速度更快，解算效率更高；当迭代不收敛时，可釆用SVD-解方程算法。  相似文献   

Study of irregular wave run-up over fringing reefs based on a shock-capturing Boussinesq model     

《Applied Ocean Research》2019

This paper presents the results of a parametric study of irregular wave run-up over fringing reefs using the shock-capturing Boussinesq wave model Funwave-TVD to better understand the role of fringing reefs in the mitigation of wave-driven flooding. Laboratory experiments were newly performed with a typical fringing reef profile and typical hydrodynamic conditions to validate the model. Experimental data shows irregular wave run-ups are dominated by the low-frequency motions and confirms the run-up resonant phenomenon over the back-reef slope, which has been revealed in previous numerical studies. It is demonstrated that irregular wave evolution and run-up over fringing reefs are reasonably reproduced by the present model with a proper grid size. However, the infragravity run-up height and highest 2% run-up height over the back-reef slope are under-predicted due to the underestimation of the infragravity wave height over the reef flat. The validated model was then utilized to model irregular wave transformations and run-ups under different conditions. Through a series of numerical experiments, the effects of key hydrodynamic and reef geometry parameters, including the reef flat width, water depth over the reef flat, fore-reef slope angle and back-reef slope angle, on the irregular wave run-up were investigated. Variations of spectral components of irregular wave run-ups were examined to better understand the physical process underlying the effect of each parameter.  相似文献   

海岸破波带内悬沙空间分布试验研究和解析表达式     

张洋  邹志利  孙大鹏  薛武山 《海洋工程》2018,36(1):28-46

关于海岸破波带内悬沙浓度水平和垂向分布的研究对于计算海岸输沙率和地形演变具有重要意义。本研究进行了规则波、波群和不规则波三种波浪情况破波带内悬沙浓度的水平和垂向分布的试验测量。试验在大尺度波浪水槽进行,接近实际海岸波况尺度。给出了破波带内多断面悬沙垂向分布的细致测量结果,并以此为基础给出了预报实际海岸破波带内悬沙浓度水平和垂向分布解析表达式,讨论了形成这些分布的物理原因和不同波况、不同破波带区域对分布的影响。  相似文献   

Lidar-aided analysis of boreal forest backscatter at Ku band     

《International Journal of Applied Earth Observation and Geoinformation》2020

This paper analyzes the backscatter of the microwave signal in a boreal forest environment based on a Ku -band airborne Frequency-Modulated Continuous Waveform (FMCW) profiling radar—Tomoradar. We selected a half-managed boreal forest in the southern part of Finland for a field test. By decomposing the waveform collected by the Tomoradar, the vertical canopy structure was achieved. Based on the amplitude of the waveform, the Backscattered Energy Ratio of Canopy-to-Total (BERCT) was calculated. Meanwhile, the canopy fraction was derived from the corresponding point cloud recorded by a Velodyne VLP-16 LiDAR mounted on the same platform. Lidar-derived canopy fraction was obtained by counting the number of the first/ the strongest returns versus the total amount of returns. Qualitative and quantitative analysis of radar-derived BERCT on lidar-derived canopy fraction and canopy height are investigated. A fitted model is derived to describe the Ku-band microwave backscatter in the boreal forest to numerically analyze the proportion contributed by four factors: lidar-derived canopy fraction, radar-derived canopy height, the radar-derived distance between trees and radar sensor and other factors, from co-polarization Tomoradar measurements. The Root Mean Squared Error (RMSE) of the proposed model was 0.0958, and the coefficient of determination R2 was 0.912. The fitted model reveals that the correlation coefficient between radar-derived BERCT and lidar-derived canopy fraction is 0.84, which illustrates that lidar surface reflection explains the majority of the profiling /waveform radar response. Thus, vertical canopy structure derived from lidar can be used for the benefit of radar analysis.  相似文献   

300 BC-1900 AD无定河流域城镇时空格局演变   总被引：2，自引：1，他引：1  

佟彪  党安荣  许剑 《地理学报》2019,74(8):1508-1524

通过分析和整理从战国中晚期（约300 BC）至清末（约1900 AD）无定河流域历代县级及以上城址的位置、兴废年代数据,结合行政区划沿革、经济社会发展、政权更迭等资料,分析流域城镇格局的时空演变过程。研究表明：① 受气候周期性波动影响,无定河流域城镇的兴起与衰废具有明显的周期性特征,城镇几何中心的移动轨迹具有明显的“西北—东南”向潮汐性运动特征;② 城址存续年限普遍较短,具有明显的阶段性特征,流域内曾存在过4个阶段性中心城镇,中心城镇移动的方向和过程与城镇几何中心的潮汐性移动过程趋势一致;③ 流域城镇空间格局可分为3种类型,即秦汉与隋唐时期的沿河流谷地分布,宋、明两代的沿边境线与长城分布,以及元、清两代集中于流域下游分布。流域城镇未来的发展布局应重视气候变化对城镇分布的长期影响,关注区域环境的脆弱性,合理安排城镇体系发展规模与布局。  相似文献   

京津冀协同发展重要地理国情监测研究与应用     

余永欣  杨伯钢  刘博文  李立军  王星杰  张建国 《北京测绘》2020,(2):224-228

文章阐述了开展京津冀协同发展重要地理国情监测的现实背景和意义,依托地理国情普查和常态化监测,结合京津冀一体化发展需求,提出了京津冀协同发展重要地理国情监测的总体思路、研究内容、关键技术和研究方法等,并开展了京津冀地区自然生态空间变化监测、高等级公路和铁路交通网络变化监测、重点大气颗粒物污染源空间分布监测等重要地理国情信息监测研究,成果已经在京津冀地区可持续发展评价、京津冀生态文明建设、空间规划管理等工作中得到了广泛应用。  相似文献   

Parallelization of the flow-path network model using a particle-set strategy     

Fangli Zhang 《International journal of geographical information science》2019,33(10):1984-2010

High-performance simulation of flow dynamics remains a major challenge in the use of physical-based, fully distributed hydrologic models. Parallel computing has been widely used to overcome efficiency limitation by partitioning a basin into sub-basins and executing calculations among multiple processors. However, existing partition-based parallelization strategies are still hampered by the dependency between inter-connected sub-basins. This study proposed a particle-set strategy to parallelize the flow-path network (FPN) model for achieving higher performance in the simulation of flow dynamics. The FPN model replaced the hydrological calculations on sub-basins with the movements of water packages along the upstream and downstream flow paths. Unlike previous partition-based task decomposition approaches, the proposed particle-set strategy decomposes the computational workload by randomly allocating runoff particles to concurrent computing processors. Simulation experiments of the flow routing process were undertaken to validate the developed particle-set FPN model. The outcomes of hourly outlet discharges were compared with field gauged records, and up to 128 computing processors were tested to explore its speedup capability in parallel computing. The experimental results showed that the proposed framework can achieve similar prediction accuracy and parallel efficiency to that of the Triangulated Irregular Network (TIN)-based Real-Time Integrated Basin Simulator (tRIBS).  相似文献